染料敏化型太陽能電池專題系列(二) 023 主要文獻中之敏化染料01

此系列文章介紹的是文獻中重要之敏化染料，分成七個篇幅介紹66支染料，如有遺漏還請各位見諒。

1. 3d
Type：polyene
Color/solution：violet
Color/on TiO2：red
Laboratory：Nippon kayaku & Yanagida
Reference：Takayuki Kitamura, Masaaki Ikeda, Koichiro Shigaki, Teruhisa Inoue, Neil A. Anderson, Xin Ai, Tianquan Lian, and Shozo Yanagida, Phenyl-Conjugated Oligoene Sensitizers for TiO2 Solar Cells., Chemistry of Materials:a Publication of the American Chemical Society, Vol. 16(9), 1806-1812, 2004
http://pubs.acs.org/cgi-bin/abstract.cgi/cmatex/2004/16/i09/abs/cm0349708.html


2. Anthocyanine
Laboratory：Michael Graetzel
Reference：Nerine J. Cherepy, Greg P. Smestad, Michael Graetzel, and Jin Z. Zhang, Ultrafast electron injection: Implications for a photoelectrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nanocrystalline electrode., Journal of Physical Chemistry B, Vol.101, 9342, 1997
http://www.solideas.com/papers/JPhysChemB.pdf


3. C217
Type：organic
HOMO/V vs SCE：-4.93
LUMO/V vs SCE：-3.45
Laboratory：Peng Wang
Rremark：9.8%(with AR)
Reference：Guangliang Zhang, Hari Bala, Yueming Cheng, Dong Shi, Xueju Lv, Qingjiang Yu and Peng Wang., High efficiency and stable dye-sensitized solar cells with an organic chromophore featuring a binary π-conjugated spacer, Chemical Communications, 2198-2200, 2009
http://pubs.rsc.org/en/Content/ArticleLanding/2009/CC/b822325d



4. CYC-B1
Type：Ru complex
ε/mol-1･cm-1：35800 DMF, 46400 DMF, 21200 DMF
λmax/nm：at 312, at 400, at 553
HOMO/V vs SCE：5.10
LUMO/V vs SCE：3.52
Laboratory：Chun-Guey Wu (吳春桂, 中央大學化學系)
Rremark：8.54% vs 7.70%(N3)
Reference：Chia-Yuan Chen , Shi-Jhang Wu, Chun-Guey Wu, Jian-Ging Chen , and Kuo-Chuan Ho, A Ruthenium Complex with Superhigh Light-Harvesting Capacity for Dye-Sensitized Solar Cells., Angewandte Chemie International Edition, Vol. 45(35), 5822-5825, September 4, 2006
http://www3.interscience.wiley.com/cgi-bin/abstract/112729598/ABSTRACT


5. D77
Type：i ndoline
ε/mol-1･cm-1：43300 EtOH (50000 DMF)
λmax/nm：at 483 EtOH (at 491 DMF)
Color/solution：red
Color/on TiO2：red
Laboratory：Mitsubishi Paper Mills Limited & Uchida
Rremark：mp. 236 deg.C
Reference：Tamotsu Horiuchi, Hidetoshi Miura and Satoshi Uchida, Proceedings of the Dye Solar Cell Osaka ICP-21 Pre-symposium. Dedicated to Professor Shozo Yanagida on the occasion of his retirement., Journal of Photochemistry and Photobiology A, Chemistry, Vol.164(1-3), 29-32,1 June 2004

6. D102
Type：indoline
ε/mol-1･cm-1：55800 t-BuOH/AcN(1/1) (61000 DMF)
λmax/nm：at 491 (at 494 DMF)
Color/solution：red
Color/on TiO2：red
Laboratory：Mitsubishi Paper Mills Limited & Uchida
Rremark：mp. >250 deg.C
Reference：Tamotsu Horiuchi, Hidetoshi Miura and Satoshi Uchida, Highly-efficient metal-free organic dyes for dye-sensitized solar cells., Chemical Communications, 3036-3037, 2003
http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b307819a
L. Schmidt-Mende, U. Bach, R. Humphry-Baker, T. Horiuchi, H. Miura, S. Ito, S. Uchida, M. Grätzel, Organic dye for highly efficient solid-state dye-sensitized solar cells., Advanced Materials, Vol. 17(7),813-815, 4 Apr 2005
http://www3.interscience.wiley.com/cgi-bin/abstract/110433867/ABSTRACT

7. D120
Type：indoline
HOMO/V vs SCE：red
LUMO/V vs SCE：red
Laboratory：Mitsubishi Paper Mills Limited & Uchida
Rremark：mp. >226 deg.C
Reference：Tamotsu Horiuchi, Hidetoshi Miura and Satoshi Uchida, Highly efficient metal-free organic dyes for dye-sensitized solar cells., Journal of Photochemistry and Photobiology. A, Chemistry, Vol. 164(1-3), 29-32, 2004



8. D131
Type：indoline
ε/mol-1･cm-1：50000 MeOH
λmax/nm：at 425 MeOH
HOMO/V vs SCE：yellow
LUMO/V vs SCE：yellow
Laboratory：Mitsubishi Paper Mills Limited & Uchida



9. D149
Type：indoline
ε/mol-1･cm-1：68700 t-BuOH/AcN(1/1) (68000 DMF)
λmax/nm：at 526 (at 541 on TiO2) (at 531 DMF)
HOMO/V vs SCE：red
LUMO/V vs SCE：purple
Laboratory： Mitsubishi Paper Mills Limited & Uchida
Reference：Tamotsu Horiuchi, Hidetoshi Miura, Kouichi Sumioka, and Satoshi Uchida, High Efficiency of Dye-Sensitized Solar Cells Based on Metal-Free Indoline Dyes., Journal of the American Chemical Society, Vol. 126(39), 12218 -12219, 2004
http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2004/126/i39/abs/ja0488277.html
S. Ito, S. M. Zakeeruddin , R. Humphry-Baker, P. Liska, R. Charvet, P. Comte, M. K. Nazeeruddin, P. Péchy, M. Takata, H. Miura, S. Uchida, and M. Grätzel, High-Efficiency Organic-Dye-Sensitized Solar Cells Controlled by Nanocrystalline-TiO2 Electrode Thickness., Advanced Materials, Vol. 18(9), 1202-1205, 2006
http://www3.interscience.wiley.com/cgi-bin/abstract/112597414/ABSTRACT?CRETRY=1&SRETRY=0

10. D150
Type：indoline
HOMO/V vs SCE：dark bluepurple
LUMO/V vs SCE：black
Laboratory：Mitsubishi Paper Mills Limited & Uchida
Reference：Tamotsu Horiuchi, Hidetoshi Miura, Kouichi Sumioka, and Satoshi Uchida, High Efficiency of Dye-Sensitized Solar Cells Based on Metal-Free Indoline Dyes., Journal of the American Chemical Society, Vol. 126(39), 12218 -12219, 2004
http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2004/126/i39/abs/ja0488277.html