染料敏化型太陽能電池專題系列(二) 026 主要文獻中之敏化染料04

此系列文章介紹的是文獻中重要之敏化染料，分成七個篇幅介紹66支染料，如有遺漏還請各位見諒。

31. K73
Type：Ru complex
Laboratory：Michael Graetzel
Reference：Daibin Kuang, Seigo Ito, Bernard Wenger, Cedric Klein, Jacques-E Moser, Robin Humphry-Baker, Shaik M. Zakeeruddin, and Michael Graetzel, High Molar Extinction Coefficient Heteroleptic Ruthenium Complexes for Thin Film Dye-Sensitized Solar Cells., Journal of the American Chemical Society, Vol. 128(12), 4146-4154, 2006
http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2006/128/i12/abs/ja058540p.html

32. K77
Type：Ru complex
Laboratory：Michael Graetzel
Rremark：highly stable
Reference：D. Kuang, C. Klein, S. Ito, J.-E. Moser, R. Humphry-Baker, N. Evans, F. Duriaux, C. Grätzel, S. M. Zakeeruddin , and M. Grätzel, High-Efficiency and Stable Mesoscopic Dye-Sensitized Solar Cells Based on a High Molar Extinction Coefficient Ruthenium Sensitizer and Nonvolatile Electrolyte., Advanced Materials, Vol. 19(8), 1133-1137, 2007
http://www3.interscience.wiley.com/cgi-bin/abstract/114210647/ABSTRACT

33. Mc[18,1]
Full name：3-carboxymethyl-5-[2-(3-octadecyl-2-benzothiazolinyldene) ethylidene]-2-thioxo-4-thiazolidinone
Type：Merocyanine
ε/mol-1･cm-1：EtOH
λmax/nm：at 520
Laboratory：Hayashibara & National Institute of Advanced Industrial Science and Technology
Reference：Kazuhiro Sayama, Kohjiro Hara, Hideki Sugihara, Hironori Arakawa, Nahoko Mori, Makoto Satsuki, Sadaharu Suga, Shingo Tsukagoshi and Yoshimoto Abe, Photosensitization of a porous TiO2 electrode with merocyanine dyes containing a carboxyl group and a long alkyl chain., Chemical Communications, 1173-1174, 2000
http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b001517m

Kazuhiro Sayama, Shingo Tsukagoshi, Kohjiro Hara, Yasuyo Ohga, Akira Shinpou, Yoshimoto Abe, Sadaharu Suga, and Hironori Arakawa, Photoelectrochemical Properties of J Aggregates of Benzothiazole Merocyanine Dyes on a Nanostructured TiO2 Film,, Journal of Physical Chemistry B, Vol. 106(6), 1363-1371, 2002
http://pubs.acs.org/doi/abs/10.1021/jp0129380



34. N3
Full name：cis-di(thiocyanato)-bis(2,2'-bipyridyl-4,4'-dicarboxylic acid)-ruthenium(II)
Type：Ru complex
ε/mol-1•cm-1：48200 EtOH, 14000 EtOH, 14200 EtOH, 13900t-BuOH/AcN(1/1)
λmax/nm：at 314, at 389, at 534, at 541
Color/solution：violet
Color/on TiO2：red
Laboratory：Michael Graetzel
Rremark：red dye
Reference：Brian O'Regan and Michael Graetzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films., Nature, Vol. 353, 737-740, 1991
http://www.nature.com/nature/journal/v353/n6346/abs/353737a0.html
M. K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Mueller, P. Liska, N. Vlachopoulos, and M. Graetzel, Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes., Journal of the American Chemical Society, Vol. 115(14), 6382-6390, 1993

Md. K. Nazeeruddin, S. M. Zakeeruddin, R. Humphry-Baker, M. Jirousek, P. Liska, N. Vlachopoulos, V. Shklover, Christian-H. Fischer, and M. Grätzel, Acid-Base Equilibria of (2,2'-Bipyridyl-4,4'-dicarboxylic acid)ruthenium(II) Complexes and the Effect of Protonation on Charge-Transfer Sensitization of Nanocrystalline Titania., Inorganic Chemistry, Vol. 38 (26), 6298-6305, 1999
http://pubs.acs.org/cgi-bin/abstract.cgi/inocaj/1999/38/i26/abs/ic990916a.html


35. N621
Full name：cis-di(thiocyanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid) (4,4'-ditridecyl-2,2'-bipyridyl)-ruthenium(II)
Type：Ru complex
Laboratory：Michael Graetzel
Reference：Mohammad K. Nazeeruddin, Filippo De Angelis, Simona Fantacci, Annabella Selloni, Guido Viscardi, Paul Liska, Seigo Ito, Bessho Takeru, and Michael Graetzel, Combined Experimental and DFT-TDDFT Computational Study of Photoelectrochemical Cell Ruthenium Sensitizers., Journal of the American Chemical Society, Vol. 127 (48), 16835-16847, 2005
http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2005/127/i48/abs/ja052467l.html
M. K. Nazeeruddin, D. Di Censo, R. Humphry-Baker, and M. Grätzel, Highly Selective and Reversible Optical, Colorimetric, and Electrochemical Detection of Mercury(II) by Amphiphilic Ruthenium Complexes Anchored onto Mesoporous Oxide Films., Advanced Functional Materials, Vol. 16(2) , 189-194, 2005
http://www3.interscience.wiley.com/cgi-bin/abstract/112191806/ABSTRACT?CRETRY=1&SRETRY=0




36. N712
Type：Ru complex
Laboratory：Michael Graetzel
Rremark：N3[TBA]4
Reference：Md. K. Nazeeruddin, R. Humphry-Baker, P. Liska, and M. Grätzel, Investigation of Sensitizer Adsorption and the Influence of Protons on Current and Voltage of a Dye-Sensitized Nanocrystalline TiO2 Solar Cell., Journal of Physical Chemistry B, Vol. 107(34), 8981-8987, 2003
http://pubs.acs.org/doi/abs/10.1021/jp022656f


37. N719
Full name：cis-di(thiocyanato)-bis(2,2'-bipyridyl-4-carboxylate-4'-carboxylic acid)-ruthenium(II)
Type：Ru complex
ε/mol-1･cm-1：45900 EtOH, 13300 EtOH, 13000 EtOH,
λmax/nm：at 308, at 380, at 518
Color/solution：violet
Color/on TiO2：red
Laboratory：Michael Graetzel
Rremark：(red dye)
Reference：Dye Solar Cell Osaka Pre- symposium, 2003.7.28



38. N749
Full name：(2,2':6',2' '-terpyridine-4,4',4' '-tricarboxylate)ruthenium(II) tris(tetrabutylammonium) tris(isothiocyanate)
Type：Ru complex
ε/mol-1･cm-1：6000 H2O, 7320 can, 7480 EtOH, 7900 DMF
λmax/nm：at 570, at 605, at 605, at 609
Color/solution：black
Color/on TiO2：black
Laboratory：Michael Graetzel
Rremark：black dye
Reference：Mohammad K. Nazeeruddin, Peter Péchy, Thierry Renouard, Shaik M. Zakeeruddin, Robin Humphry-Baker, Pascal Comte, Paul Liska, Le Cevey, Emiliana Costa, Valery Shklover, Leone Spiccia, Glen B. Deacon, Carlo A. Bignozzi, and Michael Graetzel, Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO2-Based., Journal of the American Chemical Society, Vol. 123(8), 1613-1624, 2001
http://pubs.acs.org/doi/abs/10.1021/ja003299u
Kohjiro Hara, Takeshi Nishikawa, Kazuhiro Sayama, Kenichi Aika and Hironori Arakawa, Novel and Efficient Organic Liquid Electrolytes for Dye-sensitized Solar Cells Based on a Ru(II) Terpyridyl Complex Photosensitizer., Chemistry Letters, Vol. 32(11), 1014, 2003
http://www.jstage.jst.go.jp/article/cl/32/11/32_1014/_article


39. N820
Full name：cis-di(thiocyanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)(4,4'-dimethyl-2,2'-bipyridyl)-ruthenium(II)
Type：Ru complex
Laboratory：Michael Graetzel





40. N823
Full name：cis-di(thiocyanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid) (4,4'-dihexyl-2,2'-bipyridyl)-ruthenium(II)
Type：Ru complex
Laboratory：Michael Graetzel